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V.35,no.4,Dec 2023 |
https://doi.org/10.5764/TCF. |
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Journal |
Textile Coloration and Finishing |
Year / Vol., Issue, Month |
2022 / V.34,no.1,Mar |
Title |
Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Fabrics Using Vinyl Bisphosphonic Acid and Acrylamide |
Authors |
Mi-Ji Jang and Jinho Jang |
Institution/Affiliations |
Kumoh National Institute of Technology |
Pages/Total page |
pp.1 ~ 9 / 9 |
Language |
Korean |
Abstract |
The durable FR treatments such Pyrovatex and Proban have been used for cotton fibers, while the finishes involve toxic ammonia or formaldehyde release during finishing process or finished products. In this study, ecofriendly flame-retardant treatment of cotton fabrics was carried out using UV-curable formulations of Vinyl bisphosphonic acid (VBPA), Acrylaminide and Triacryloylhexahydro-1,3,5-triazine, as a monomer, a comonomer and a cross-linking agent respectively, which can introduce a cross-linked copolymer networks. With an optimal finish formulation, the flame retardancy of LOI 29.8 was maintained even after 10 laundering cycles. In TGA analysis, the DTGA peak decreased from 389¡É to 252¡É and the amount of char yield increased from 6.1% to 46.1% compared to the untreated cotton. In addition, MCC analysis showed that Peak HR and THR decreased by 59.4% and 69.2% respectively, compared to the untreated cotton. The pyrolysis and combustion behaviors of the FR-treated cotton implied a condensed-phase flame-retarding mechanism. |
Keywords |
formaldehyde-free, durable, flame-retardant, cotton, vinyl bisphosphonic acid, acrylamid |
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Reference |
http://koreascience.or.kr/journal/OSGGBT.page?&lang=ko |
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